The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / ClO / Porter(1950)_298K_263.63-303.45nm(band heads)

DATAFILE: ClO_Porter(1950)_298K_263.63-303.45nm(band heads).txt
NAME: chlorine monoxide
FORMULA: ClO
AUTHOR(YEAR): Porter(1950)
T: 298K
λ: 263.63-303.45nm(band heads)
BIBLIOGRAPHY: G. Porter, "The absorption spectroscopy of substances of short life", Discuss. Faraday Soc. 9, 60-69 (1950); DOI: 10.1039/DF9500900060
COMMENTS: The relative intensities of the absorption cross-sections at the band heads of the strong progression from v" = 0 were placed by

R.T. Watson, "Rate constants for reactions of ClOx of atmospheric interest," J. Phys. Chem. Ref. Data 6, 871-917 (1977); DOI: 10.1063/1.555558

on an absolute basis by equating the value at 277.16 nm to that reported by

M.A.A. Clyne and J.A. Coxon, "Kinetic studies of oxy-halogen radical systems," Proc. Roy. Soc. London A 303, 207-231 (1968); DOI: 10.1098/rspa.1968.0048

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